Polymer Laboratory
Research Topics
Electrospinning of Carbon Nanotube Reinforced Polymeric Materials
The electrospinning process will be used to embed multi-walled carbon nanotubes (MWCNTs) in a Polyvinylpyrrolidone (PVP) matrix, forming composite nanofibers. Initial dispersion of MWCNTs in water will be achieved by the use of surfactants. Different surfactants will be used in order to achieve the highest amount of MWCNTs being dispersed in the polymer solution. The efficiency of the surfactants will be examined as well as their effects on the electrospinning process. After electrospinning, the morphology of the electrospun nanofibers and the distribution and conformation of the MWCNTs in the nanofibers will be studied by Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). The elastic modulus of the electrospun composite fibers will be measured using AFM. It is expected that the presence of aligned and unagglomerated MWCNTs will improve the mechanical properties dramatically.
Effects of Molecular Weight Distribution on the Formation of Fibers of Electrospinning Polystyrene
It is widely recognized that molecular weight distribution (MWD) is an important factor affecting the rheological behavior of polymer solutions. The objective of this research is to study the effects of MWD on the formation of electrospun polystyrene fibers in THF. The results will be compared with the monodisperse system. A quantitative relationship between chain entanglements attributed to high molecular weight component and the rheological properties of the polydisperse system will be established. Concentrations for the incipient as well as stable fiber formation in a polydisperse system may be predicted.
Drug Coated Stents
The objective of this research is to analyze the drug release
kinetics between drug-coated stents. The stents are coated by
different methods. A polymer-drug is electrospun onto
the stent mesh to form a coating composed of submicron sized polymer
fibers. Another
non-polymer drug attachment is achieved through anodization. SEM
is used to analysis distribution and morphologies of the
coatings. Spectroscopy is then used to analyze the drug release
kinetics. The release profiles of both methods are obtained. The
releasing efficiencies achieved from different coating methods are
compared.
SEM micrograph shows a drug coated stent (Boston Scientific)
Completed Research Projects
For more information on completed research projects, click on the links below:
- Flight path of electrospun polystyrene solutions: Effects of molecular weight and concentration
- Solvent Effects on Jet Evolution during Electrospinning of Semi-dilute Polystyrene Solutions
- Bead-to-Fiber Transition in Electrospun Polystyrene
- Electrospinning of Biopolymers (Project research by Chen-Ming Hsu and Jing Tao)
- Submicron-scale poly(E-caprolactone) fibers produced by electrospinning (Project research by Chen-Ming Hsu)
Electrospinning of Polystyrene
Electrospinning of Biopolymers
Contact Information
Polymer Laboratory
Washburn Shops
Rms. 250, 251
WPI
100 Institute Road
Worcester, MA 01609
Phone: 508-831-5817
Fax: 508-831-5178
Faculty Information
For more information, contact Prof. Satya Shivkumar, shivkuma@wpi.edu
Last modified: Mar 05, 2007, 13:15 EST
